Heavy Metal Solidification/Stabilization
Technical Principle: By mixing chemical agents (solidifiers) with tailings slag, heavy metal ions are converted into insoluble compounds to block their migration.
Key Steps:
Pretreatment: Screen the tailings slag to remove large particle impurities;
Agent Addition:
Inorganic solidifiers: Cement, fly ash (forming a silicate network to encapsulate heavy metals);
Organic solidifiers: Sulfides (e.g., Na₂S), phosphates (generating precipitates such as Pb₃(PO₄)₂);
New materials: Geopolymers (with better acid and alkali resistance than cement).
Mixing and Curing: Control the moisture content (15-20%) and cure for more than 7 days to form a solidified body.
Engineering Solidification for Pit Backfilling
Layered Compaction: The filling thickness of each layer is ≤ 0.5m, and mechanical compaction is performed to achieve a compactness of > 90% to prevent collapse.
Anti-seepage Barrier: Lay an HDPE membrane (2mm thick) + bentonite cushion (GCL) at the pit bottom to block the downward seepage of heavy metals;
The side walls are protected with shotcrete (thickness 10-15cm).
Monitoring System: Embed leachate collection pipes + water quality sensors (to monitor pH and heavy metal concentrations in real time).
Substrate Improvement
Physical improvement: Cover with 30-50 cm of soil (or mix foreign soil with tailings slag at a 1:1 ratio) and incorporate straw/sludge (to increase organic matter).
Chemical improvement: Add quicklime (to adjust pH to 6.5-7.5); apply passivators (hydroxyapatite to passivate cadmium, zeolite to adsorb arsenic).
Vegetation Reconstruction
Selection of pioneer plants: For example, heavy metal-accumulating plants to absorb/fix pollutants; barren-tolerant herbs to quickly cover the surface; nitrogen-fixing shrubs to improve soil fertility.
Planting techniques:
Hydroseeding: Mix substrate + seeds + binder and spray (for areas with a slope > 30°);
Ecological blankets: Cover with coconut fiber blankets to retain water (suitable for arid regions).
Water-Fertilizer System and Long-Term Management
Micro-irrigation system: Lay drip irrigation tapes, combined with slow-release fertilizers (N-P₂O₅-K₂O = 15-15-15).
Ecological monitoring: Test the heavy metal content in vegetation quarterly (e.g., arsenic in Pteris vittata leaves should be < 100 mg/kg) to prevent pollution spread.
Prevention of Secondary Release of Heavy Metals:
Before greening, it is necessary to ensure that the pH of tailings slag is > 6.0 (to avoid heavy metal leaching by acid water);
Vegetation shall be incinerated after harvesting (with ashes disposed of in safe landfills).
Guarantee of Slope Stability:
When the slope is > 35°, lattice beams + anchor bolts shall be installed for support;
Deep-rooted shrubs (such as Caragana korshinskii) shall be planted to reinforce the soil layer.